Lord of the molecular rings created |
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"There was a bit of a friendly race going on to
see who would get there first." Holy trinity Borromean rings have symbolised
the holy trinity in Christian iconography, the heart of a giant in Nordic
mythology, and the crest of the Borromeo family in 15th-century Tuscany.
"Our inspiration was partly the sheer beauty of the molecules and partly
their potential to be turned into some of the smallest possible machines
and switches you can design at the molecular level," Stoddart told New Scientist
. "Chains and links are important for making gears and switching devices,"
agrees Jay Siegel, a chemist at the University of Zurich, Switzerland, who
was not part of the team. "But the real advance here is the synthetic skills
that allow a whole variety of ringed structures to be made." Spontaneous assembly Rather than building the rings one at a time, Stoddart's team used zinc ions to nudge three component parts to come together spontaneously. The result was a Borromean ring with a diameter of 2.5 nanometres and an inner chamber lined with 12 oxygen atoms. "The compound makes itself because it is very much more stable than any of its competitors," he says. Computer modelling played a vital role in the molecule's design. "Not one atom changed its type or place in the molecular structure between going from the computer to the laboratory. This experience is still an extremely rare one," says Stoddart, whose results are published in Science . In the same issue of Science , a team led by Leyong Wang of Johannes Gutenberg University in Mainz, Germany, report creating two molecules, each made of four interlinked rings. Applications from the research are still a long way off, says Stoddart. "But as soon as we have a clear line of sight to a widget, we will head straight for it with a vengeance." Journal reference: Science (vol 304, pp 1308 and 1312) |
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