Buckyballs open a whole new game

The merest specks of soot are sweeping chemists of their feet
Footballers with Fullerene

Why God had a ball making the universe
God, it seems, loves the beautiful game - when he fashioned the universe he made it the shape of a football. The cosmos is not infinite - but a finite 'soccer ball' of curved pentagons joined together, scientists claimed yesterday. In an attempt to kick into touch all other theories about the shape of the universe, NASA experts said it was 'positively curved' . They described it as like a hall of mirrors, endlessly reflecting itself . In this closed dodecahedron - a 12-faced object - a spacecraft exiting through one pentagon would re-enter the same region through the opposite face and would meet the same galaxies over and over again. If confirmed, the results would mean the universe is much smaller than believed and about 70 billion light years across. The findings are based on data collected by a NASA spacecraft, the Wilkinson Microwave Anistropy Probe, mapping the radiation left over from the Big Bang. Current cosmos theories include one which proposes the Earth's 'local' universe is one of many expanding bubbles. Other observations suggest that it is 'flat' - meaning parallel lines stay the same distance apart and never meet. Another view is that it is spherical but in three dimensions - so if you could look through a very powerful telescope you would see the back of your head. The new theory challenges all those ideas, says leading US mathematician Dr Jeffrey Weeks. 'Since antiquity humans have wondered whether out universe is finite or infinite,' he told journal Nature. 'Now, after more than two millennia of speculation, observational data might finally settle this ancient question.
[The Metro 9Oct 2003]

When a candle burns,it is the beauty of the bright flame that attracts our attention. But ask a chemist where the real beauty lies and the answer will come as a surprise: it is in the candle's soot.

For lurking in the black deposits are tiny amounts of buckminsterfullerene,a ball like arrangement of carbon atoms discovered in 1985 and now considered by chemists to be The Most Beautiful Molecule.

It is 10 years since their discovery but "buckyballs" - which are named after the innovative American architect Buckminster Fuller,whose domed structures bear an uncanny likeness to the molecules - are still one of the hottest topics in chemistry.

There are many possible applications for the buckyballs,ranging from rocket fuel to anti-Aids medicine,and new discoveries about them are emerging in research literature at the rate of around one a day.

Yet the story of their discovery is a classic case of "useless" science producing something quite unexpected and of huge commercial potential.This week sees the publication of two books describing that story.

According to Dr Jim Baggot,author of one of them - Perfect Symmetry :the accidental discovery of buckminsterfullerene (Oxford University Press) - the first inklings of the existence of buckyballs appeared in,of all places,a humorous article in the New Scientist magazine in 1966.

Written by David Jones,himself a scientist,the article centred on a curious "desert" of materials with densities somewhere between those of gases - which are typically a thousand times less dense than water - liquids and solids.

Mr Jones suggested that molecules of a material like carbon might,if curled up like a ball,bridge this huge gap.
His suggestion proved astonishingly accurate.In 1985,Dr Harry Kroto of Sussex University was working with colleagues at Rice University in Houston investigating the apparently esoteric problem of forming  large carbon molecules in deep space.

They were trying to explain observations suggesting that clouds of such molecules were lurking in the cosmos,mopping up light from stars.
 Dr Kroto and his co-workers tried to make these large molecules in the laboratory by blasting graphite using laser beams.

They discovered that,for some reason,they were producing a preponderance of one type of carbon molecule,containing 60 carbon atoms.
 Why so huge a molecule should be found in such numbers was a complete mystery: its chemically reactive "edges" should have led it to almost immediate annihilation.

But then Dr Kroto and his colleagues had a brainwave: perhaps the molecule was folding up inot a ball,thus connecting up all its reactive edges.
 After much playing with cardboard models,the team finally succeeded in getting the right shape.

Carbon- 60 is indeed a ball of carbon atoms,its surface made up of hexagons and pentagons - just like a football.


According to Hugh Aldersey-Williams,the author of the second book on the discovery (The Most Beautiful Molecule,Aurum Press),this led the research team to consider names like ballene,spherene and soccerene

In the end the unwieldy buckminsterfullerene has,however stuck - and deprived headline writers everywhere of a feast of invention.
 Now the search is on for applications.By trapping atoms inside the "cage" of buckminsterfullerene,scientists hope to create molecular switches and memories for storing data.

By adding impurities,they have also found that bucky balls become "superconductors",losing all their electrical resistance at very low temperatures.
Both may have long-term technological uses.

Speaker Icon WAV 259K

Researchers at the University of California last year showed that a water-soluble form of the molecule fits neatly into the crevices of the Aids virus,blocking its activity.

Among the more bizarre applications is rocket fuel: by accelerating them electrically and ejecting them out of the back of a spaceship,the relatively dense and pellet-like buckyballs may be an ideal propellant for very long spaceflight.

Technologists are now trying to turn such possibilities into reality.If they succeed,it will be a salutary lesson in the value of "useless" science.

"At the root,this is a story of classic "bootleg" science," points out Mr Aldersey-Williams."The work was done on the back of other funded projects and when time would allow.Yet its commercial implications are probably immense."


Robert Matthews

Sunday Telegraph

Faux Fullerenes

Like a newly learned word that seems to jump from every book molecular cages have become ubiquitous since the existence of buckminsterfullerene's icosahedral carbon cage was confirmed two years ago. First came larger carbon cages called giant fullerenes; nested cages, known as Russian dolls; and ultrathin fibers, called buckytubes. Next were the metallofullerenes-hybrids that encase metal atoms or incorporate them in the carbon lattice itself. Now the synthesis of a carbonless envelope has been announced: a nested cage of tungsten disulfide [see illustration below].

Uncarbonated Fulleroid consists of nested cages of the semiconductor tungsten disulfide.

The faux fullerenes first appeared in July 1991 at Israel's Weizmann Institute of Science where Reshef Tennep Lev Margulis, Menachem Genut and Gary Hodes were preparing tungsten disulfide for use in high-performance solar cells. The workers did not immediately grasp the importance of the nested balls of the semiconductor material. "We saw the Russian dolls in July 1991 ," Tenne says, "but we did not make the connection until later, when we looked at the pictures made by Iijima." (Sumio Iijima of NEC Corporation described nested buckytubes late in 1991.)

As a result of the delay,the Weizmann researchers can state categorically that the mock buckystructures are stable for at least a year. But easy though they may be to keep, no one has yet produced them in bulk. Like their carbon archetypes phony fullerenes form only at high temperatures. In such a regime a vapour of tungsten disulfide condenses into a two-dimensional sheet, as do the carbon precursors of fullerenes. Some hexagonal cells then convert to pentagons, causing the sheet to curve in on itself and close.

What tricks might these motes perform if they could be made by the gram? "I guess they will show photoconductive and quantum effects," Tenne says The smallest cages of tungsten disulfide are believed to have an electronic band gap well below the 1.6 electron volts of the bulk material. "As the number of layers rises" Tenne notes "the gap should approach that value." Materials scientists can therefore hope to control the growth of the structures so as to "tune" the band gap for their electronic properties. For example one might tune the Russian dolls for optimal absorption of sunlight, producing better solar cells. Even more exciting is the prospect of tuning tungsten disulfide so that it emits visible light. The bulk form of this material cannot serve this function because it is like silicon, an indirect-gap semiconductor, in which electrons and positive charges or holes, do not normally recombine to form light.

Other possibilities also beckon. Tungsten disulfide is used as a lubricant in some aerospace applications. If it retains this property in its fulleroid form, it may serve to grease the wheels of tomorrow's nanomachines. One might for example deposit tiny greaseballs in a microscopic bushing or inside a minuscule ball-and-socket joint. Mock buckytubes might also be intercalated with lithium to form microscopic rechargeable batteries. The range of properties of fakeyballs looms even larger because other substances can also condense into sheet-like precursors. Each substance might father an entire family of shapes and sizes. "Oh, there are so many two-dimensional materials" Tenne exults. "We are trying molybdenum disulfide. Then we will go to other compounds."

-Philip E. Ross [Scientific American Feb93]

Buckyball film is no rough diamond

Thin films of buckyballs have been grown by physicists in the US. The films are smooth and soft (right picture) , quite unlike diamond films, which have a hard, jagged surface (left).

Bucky Film

The C60 films are between 200 and 300 nanometres thick. They were made by Art Hebard and his colleagues at AT&T's Bell Laboratories in Murray Hill, New Jersey. According to Hebard, the nanometre-sized buckyballs sublime easily when heated and deposit themselves on nearby surfaces.

Buckyballs are neutral overall but because they have regions of positive and negative charge, they can attract each other.
Hebard says that when a buckyball is in contact with a surface, electrons move from the surface to the buckyball, forming an ionic bond. On a silicon surface buckyballs tend to bond where they land. But on gallium arsenide, a semiconductor which is like silicon but which has a different arrangement of electrons, the buckyballs are very mobile.

The grooved pattern in the picture was etched using a technique similar to that used to print circuit patterns on silicon chips. This method involves placing a material called a photoresist on the silicon surface of the chip and then placing a mask, which contains the circuit pattern, above this.Next ultraviolet, light is shone onto the mask. Wherever the light shines through the mask it strengthens the chemical bonds in the photoresist layer below. This means that when the surface is rinsed with a solvent, it washes away only those parts of the photoresist which were unexposed to light.

Hebard found that, just like photo resist, C60 is sensitive to ultraviolet light. By shining a striped pattern of ultraviolet light onto the film, he was able to strengthen the chemical bonds in the exposed areas, making them resistant to solvent. AT&T has not yet revealed details of etching process. Hebard says there is no known use for patterned C60 films.

Elisabeth Geake
[New Scientist 12 June1993]

Non-metallic magnet could be dream computer memory

19:00 17 October 01 Justin Mullins

A transparent, flexible magnetic material made from an exotic form of carbon could turn out to be the dream computer memory. The substance, which was discovered accidentally by a Russian physicist hunting for high-temperature superconductors, is the first non-metallic magnet to work at room temperature.

Tatiana Makarova, working at Umeå University in Sweden, discovered the material while experimenting with buckyballs, football-shaped molecules made up of 60 carbon atoms. By heating and compressing the molecules, she forced them to join together in layers like sheets of bubble wrap, because she thought these might be able to superconduct.

But to her surprise, she found instead that the new material was magnetic even above 200 °C. Until now, the highest temperature at which a non-metallic material was magnetic was ­255 °C. This record was held by a different form of buckyballs.

Organic magnets could be important because they are much lighter than their metallic cousins. Also, Makarova's material is flexible and transparent, properties that could make it useful for storing data when a laser is used to record on it. It might also be possible to record data at unprecedented densities.

Mystery magnetism

Exactly why the material is magnetic is not yet clear. Makarova believes that unpaired electrons may play a crucial role, since they can sustain a magnetic field when their spins are aligned. One possibility is that the magnetism stems from buckyballs bonding in triangular groups of three.

"In this configuration, there can be unpaired spins," she says. Her team is currently comparing buckyball layers made in different ways to try to find out.

Robert Blinc, an expert on molecular magnets at the University of Ljubljana in Slovenia, says the work is a giant step forward. He says it is not yet clear whether the magnetic properties are uniform throughout the structure or occur in clumps. "But in any case it is extremely important," he says.

Journal reference : Nature (vol 413, p 716)
19:00 17 October 01


Warmer Superconducting Buckyballs

Image: courtesy of J. Lauher's Fullerene Structure Library

The marvel of superconductors is their ability to carry electricity without any loss. A superconducting ring, for example, can theoretically sustain a looping current indefinitely. The catch, however, is that most superconducting materials work only when they are supercold: traditional superconductors must be chilled to within a few degrees of absolute zero, and even so-called high-temperature superconductors--ceramics made with copper and oxygen--need to reach the temperature of liquid nitrogen, or negative 196 degrees Celsius, before they start to hum. But new hope for even higher temperature superconductors has emerged in the form of carbon soccer balls called buckminsterfullerenes, or, simply, buckyballs: scientists from Bell Laboratories report in today's issue of Nature that it may be possible to create buckminsterfullerenes that are superconducting at practical temperatures.

In the early 1990s, scientists found how to make buckyballs superconducting by doping them with metal atoms. The metals, trapped inside the buckyball's carbon sphere, release free electrons that carry current. But the highest temperature at which these metal-doped buckyballs became superconducting was about negative 255 degrees Celsius. Now Bertram Batlogg and his colleagues have raised that threshold by another 40 degrees--simply by doping the buckyballs in a different way. Instead of adding electrons with metal dopants, they removed them by injecting "holes" to molecules of C60--buckyballs containing 60 carbon atoms (see image). Holes, too, carry current and act much like electrons, except that they have a positive charge. When the scientists added about three holes per molecule of C60, the buckyballs became superconducting at negative 221 degrees Celsius. And they suspect they can raise that temperature even higher--perhaps well above that of liquid nitrogen--by using some inert dopant to push the individual buckyballs farther apart. --Kristin Leutwyler
[Scientific American 31/12/2001]

Carbon Nanotubes Could Lengthen Battery Life Carbon nanotubes—tiny tubular structures composed of a single layer of carbon atoms—could lengthen the life of batteries, according to new research. Findings published in the current issue of Physical Review Letters suggest that the diminutive tubes can hold twice as much energy as graphite, the form of carbon currently used as an electrode in many rechargeable lithium batteries. The reduction and oxidation reactions that occur at the electrodes of batteries produce a flow of electrons that generate and store energy. Conventional graphite electrodes can reversibly store one lithium ion for every six carbon atoms. To investigate the storage capacity of carbon nanotubes, Otto Zhou and colleagues at the University of North Carolina, Chapel Hill, first created bundles of the single-walled straws. They then shortened the tubes and opened their ends by immersing them in strong acids. Subsequent tests of their energy-holding potential, conducted using electrochemistry and nuclear magnetic resonance spectroscopy, revealed an electrical storage capacity approximately double that of graphite. In explanation, the scientists note that the tubes' open ends facilitated the diffusion of lithium atoms into their interiors. Indeed, the tiny straws managed to reversibly store one charged ion for every three carbon atoms. As with many findings in the nascent field of nanotechnology, commercial devices based on the work remain a ways off. "We'll have to work on and overcome other practical issues before we can make real devices," Zhou says, "but we are very optimistic." —Sarah Graham [Scientific American ]


Carbon Nanotubes Could Serve as Ultrafast Oscillators

The minuscule size of carbon nanotubes—hollow cylinders measuring a few billionths of a meter wide—can boggle the mind. Now picture the straws nestled inside one another like Matryoshka dolls, with the inner set of tubes sliding in and out a billion times a second. In fact, according to a report published in the January 28th edition of Physical Review Letters, scientists could conceivably fashion just such a gigahertz oscillator—one that could aid in the creation of nanomechanical devices.

The curious 60-atom clusters of carbon, may have found a medical niche. Modified versions of the hollow carbon balls could protect injured brain tissue by mopping up highly reactive molecules called free radicals, say researchers in the US.
After head injury or a stroke, nerve cells are killed by the overproduction of oxidising free radicals in the brain. But now Laura Dugan of Washington University School of Medicine in St Louis and her colleagues report that modified buckyballs,containing carboxyl side chains to make them water soluble, seem to protect brain tissue.
The researchers studied mice that had been genetically engineered to lack the gene for an enzyme called superoxide dismutase, which rids cells of free radicals. The hind legs of such animals usually become paralysed when they are 15 weeks old, and they die within 18 weeks.
Some of these mice received soluble buckyballs via an abdominal pump, while a control group did not. The treated animals were symptom-free 15 per cent longer tnan the control group, the team reports in the latest Proceedings of the National Academy of Sciences (vol 94, p 9434). "That makes us believe that, with better delivery systems, modified buckyballs eventually could be protective in living animals and humans," says Dugan.
Dugan's colleague Tien-Sung Lin notes that chemical studies have already suggested that buckyballs are able to swallow and retain dozens of free radicals such as peroxide. "The evidence that buckyballs can do this kind of thing is clearly there," he told New Scientist. Dugan adds that as well as acting directly on the free radicals, the buckyballs may be mopping up other chemicals that increase rates of pro grammed cell death.
Michael Day

{NS 30Aug97)

Previous work by John Cumings and Alex Zettl of the University of California, Berkeley, had shown that prying open one end of such a multiwalled nanotube transformed it into a telescoping tube: the inner tubes slid in and out of the surrounding straws with very little friction (see image). In the new study, Qing Jiang of the University of California, Riverside and Quanshui Zheng of Tsinghua University in Beijing modeled the sliding action of a tube with two open ends. Their calculations show that if the inner core were pulled out of such a tube, it would not only retract back into the center of the tube, but it would also continue right out the other end. Nearly negligible friction between the tubes would enable a breakneck gigahertz oscillation frequency, the investigators report. And shorter tubes could move at even greater speeds.

Jiang suggests that the tubes may one day make their way into fiberoptic systems as ultrafast optical filters. Before that can happen, however, researchers will have to figure out exactly how to excite the oscillator and how to couple it with the rest of the nanoscopic device. "The actual implementation of this coupling," the authors conclude, "represents another challenge in development." —Sarah Graham [Scientific American 23/1/2002]


Osmium Is Stiffer than Diamond, Scientists Discover

Whether it will compete for the title of a girl's best friend remains to be seen, but the element osmium can already challenge diamond in at least one respect: stiffness. According to a report published in the current issue of Physical Review Letters, osmium can withstand compression better than any known material. The results provide a potentially new lead in the search for superhard materials.

Diamond's ability to resist scratches, dents and chipping--in short, its hardness--makes it an ideal choice for tips in industrial-strength machines. A related quality that is easier to calculate than hardness is an element's resistance to compression, known as its bulk modulus. The properties are interrelated because the stiffest materials also tend to be the hardest ones. But even though osmium is much softer than diamond, initial estimates of its bulk modulus indicated a similar value to that of diamond.

Hyunchae Cynn and colleagues at Lawrence Livermore National Laboratory thus set out to test the property experimentally. They squeezed osmium powder under 600,000 atmospheres of pressure and calculated changes in the spacing between atoms in the sample using x-ray diffraction patterns. The team reports that osmium's bulk modulus is 462 gigapascals (GPa), as compared with diamond's 443 GPa. "It is intriguing that a light, covalently bonded element such as diamond and a heavy, metallic element such as osmium, with very different chemical bonding, would both have large values of the bulk modulus," the authors note. They conclude that related compounds such as transition metal carbides, nitrides and oxides could be sources of new superhard materials. --Sarah Graham [Scientific American 2/4/2002]

Nanotube transistor "outperforms" silicon

16:02 21 May 02

NewScientist.com news service

Researchers at IBM have fabricated a carbon nanotube transistor that mimics the design of modern silicon transistors but performs much better.

Transistors are the "switches" in electronic circuits, controlling the current that represents digital information. Making transistors smaller means more can be packed into circuits, resulting in more powerful computer chips.

But silicon transistors are expected to reach their physical limit of miniaturisation in the next couple of decades. Researchers hope nanotube devices may help keep circuits shrinking towards the atomic scale.

Engineers at IBM's Watson Research Center in New York fabricated a single-walled carbon nanotube field-effect-transistor (CNFET) designed to mirror the architecture of a metal-oxide semiconductor field-effect-transistor (MOSFET). The later is very common in modern silicon circuits.

Shalom Wind, at IBM, says the new nanotube transistor differs from previous designs. He says its gate, which controls the current, is on top of a nanotube and separated from the channel by a layer of silicon dioxide, rather than being shared between a number of transistors. This makes it possible to control each transistor individually.

Current boost

The research team found that the nanotube transistor's gate could control the current better, meaning larger currents could be used. "The more current you can drive, the more flexibility you have in circuit design," Wind told New Scientist. "The implication is that you could have faster transistors."

The transistor's novel design also means the researchers were able to fabricate transistors with different polarity. This is a crucial property of complementary metal oxide-semiconductor (CMOS) circuits, which are also very common.

Cees Dekker, a carbon nanotube researcher at Delft University of Technology in the Netherlands, says this is an important step towards building practical nanotube circuits. "It's interesting to make the comparison with silicon," he says. But he warns that many parameters are important in determining the efficiency of a transistor.

At present, the nanotube transistors are not smaller than the silicon ones, but the IBM researchers claim their results are a proof of principle and that the nanotube transistors will outperform them even when shrunk.

Journal reference: Applied Physics Letters (vol 80, p 3817)

Will Knight

DIAMOND FILM COULD FORM BASIS OF HIGH-POWER ELECTRONICS They've long been a girl's best friends, but now diamonds might just win over electrical engineers, too. According to a recent report, scientists have succeeded in fabricating films of synthetic diamond that have properties similar to those of silicon. The results could lead to new carbon-based electronics. http://sciam.rsc03.net/servlet/cc?lJpDVUWEmLtisHklLkpLlFHhsDJhtE0EV

Click to search for Carbon 60

NANOTUBE DIAGNOSTIC X-RAYS. The design of the x-ray sources used in many medical and dental diagnostics hasn't changed much in a hundred years. A cathode heats up to 1500 C and then emits lots of electrons, which are pulled across a vacuum tube toward a target where the ensuing impact kicks up a beam of x rays. Now a team of physicists and doctors at the University of North Carolina and the nearby firm of Applied Nanotechnologies, Inc. have created, for the first time, an x-ray source using a room- temperature array of carbon nanotubes to create the electrons and deliver a sufficient x-ray flux for doing practical medical imaging (figure at www.aip.org/mgr/png/2002/157.htm ). The device is much smaller and cooler and the old models, and the resultant x- ray pulse is more focused. Also response time is sharper and the pulse shape can be programmed, which helps in the tracking of moving objects. (Yue et al., Applied Physics Letters, 8 July 2002; contact Otto Zhou, 919-962-3297, zhou@physics.unc.edu; text at www.aip.org/physnews/select).

Nanotube chip could hold 10 gigabits
12:47 17 June 03 NewScientist.com news service

A computer memory chip based on carbon nanotubes has passed a manufacturing milestone, according to the US company developing the technology. The prototype chip would store information using hundreds of billions of nanotubes with a theoretical capacity of 10 gigabits of data, says Nantero, based in Boston, Massachusetts. Once fully developed, the company says nanoscale random access memory (NRAM) could hold more data that existing types of RAM and would also be non-volatile, meaning data would not be lost when the power is been turned off. Computers using such memory could boot up almost instantly. Nantero also claims that NRAM would be much faster than current non-volatile memory, such as Flash. Nantero is not the only company hoping to use carbon nanotubes to make improved types of computer memory. But the company believes its advantage lies in the fact that its chips can be made using existing silicon manufacturing methods and would therefore be relatively cheap to make. Random arrangement Instead of trying to grow nanotubes in the correct alignment, Nantero applies them randomly across the entire surface of a silicon wafer. It then uses existing lithographic equipment to etch away the nanotubes that are not in the correct alignment. "The creative breakthrough is to put nanotubes everywhere," Nantero's CEO Greg Schmergel told New Scientist. The nanotubes remaining after etching are arranged in bunches across pairs of electrodes on the surface of the wafer. Applying a small electrical field alters the tubes so that they either bridge the gap between the electrodes or do not. These two states result in different conductivity that is easy to detect and can be used to represent a binary one or zero. Nantero has now produced a wafer dotted with nanotube clumps, but is still developing the way of addressing each individual bunch. Schmergel says this is just a matter of harnessing existing silicon electronics technology. Cees Dekker, an expert in carbon nanotubes at Delft University in the Netherlands, says the fabrication technique appears workable. But he says a potential problem lies in the difficulty of separating the different types of nanotubes that are created together during their creation. "You have to find a way to deal with both semiconducting- and metallic-type nanotubes, which have rather different electrical properties," he told New Scientist. Schmergel expects to have NRAM memory capable of storing up to four megabits in 18 months and components that could compete with current types of RAM in around three years.
Will Knight





Chaos Quantum Logic Cosmos Conscious Belief Elect. Art Chem. Maths

File Info: Created --/--/-- Updated 17/3/2016 Page Address: http://leebor2.100webspace.net/Zymic/buckball.html